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Liste der wissenschaftlichen Veröffentlichungen
Professor Dr. Bernd Speiser

  1. B. Speiser und A. Rieker, J. Chem. Res. (S) 1977, 314 - 315; (M) 1977, 3601 - 3609; Electrochemical Oxidations. Part 1. Phenoxy Cations in the Anodic Oxidation of Phenolic Compounds.
  2. B. Speiser und A. Rieker, Electrochim. Acta 23, 983 - 989 (1978); Elektroanalytische Untersuchungen - I. Die Auswirkung von Kanteneffekten auf die Zahl der Peaks in cyclischen Voltammogrammen.
  3. B. Speiser und A. Rieker, J. Electroanal. Chem. 102, 1 - 20 (1979); Electroanalytical Investigations. Part II. Application of the Orthogonal Collocation Technique to the Simulation of Cyclic Voltammograms.
  4. B. Speiser und A. Rieker, J. Electroanal. Chem. 102, 373 - 395 (1979); Electrochemical Oxidations. Part IV. Electrochemical Investigations into the Behaviour of 2,6-Di- tert-butyl-4-(4-dimethylaminophenyl)-phenol. Part 1. Phenol and the Species Derived from it: Phenoxy Radical, Phenolate Anion and Phenoxenium Cation.
  5. B. Speiser, J. Electroanal. Chem. 110, 69 -77 (1980); Electroanalytical Investigations. Part III. Optimization of the Dimensionless Parameter $\beta$ in Orthogonal Collocation Simulations of Cyclic Voltammograms.
  6. B. Speiser und A. Rieker, J. Electroanal. Chem. 110, 231 - 246 (1980); Electrochemical Oxidations. Part V. Electrochemical Investigations into the Behaviour of 2,6-Di- tert-butyl-4-(4-dimethylaminophenyl)-phenol. Part 2. Anodic Oxidation in the Presence of 2,6-Dimethylpyridine and the Mechanism of the Formation of the Phenoxenium Cation.
  7. B. Speiser, Chemie in uns. Zeit 15, 21 - 26 (1981); Elektroanalytische Methoden. I. Grundlagen und Chronoamperometrie.
  8. B. Speiser, Chemie in uns. Zeit 15, 62 - 67 (1981); Elektroanalytische Methoden. II. Cyclische Voltammetrie.
  9. B. Speiser und S. Pons, Can. J. Chem. 60, 1352 - 1362 (1982); Simulation of Edge Effects in Electroanalytical Experiments by Orthogonal Collocation. Part 1. Two-dimensional Collocation and Theory for Chronoamperometry.
  10. B. Speiser und S. Pons, Can. J. Chem. 60, 2463 - 2476 (1982); Simulation of Edge Effects in Electroanalytical Experiments by Orthogonal Collocation. Part 2. Theory for Cyclic Voltammetry.
  11. B. Speiser, A. Rieker und S. Pons, Electrochim. Acta 27, 1171 - 1176 (1982); Electroanalytical Investigations. - IV. Use of Orthogonal Collocation for the Simulation of Quasireversible Electrode Processes under Potential Scan Conditions.
  12. S. Pons, B. Speiser und J.F. McAleer, Electrochim. Acta 27, 1177 - 1179 (1982); Orthogonal Collocation Simulation of the Rotating Disk Electrode.
  13. S. Pons, B. Speiser, J.F. McAleer und P.P. Schmidt, Electrochim. Acta 27, 1711 -1714 (1982); Simulation of the Dropping Mercury Electrode by Orthogonal Collocation.
  14. B. Speiser und S. Pons, Can. J. Chem. 61, 156 -162 (1983); Simulation of Edge Effects in Electroanalytical Experiments by Orthogonal Collocation. Part 3. Application to Chronoamperometric Experiments.
  15. B. Speiser, A. Rieker und S. Pons, J. Electroanal. Chem. 147, 205 - 222 (1983); Electrochemistry of Anilines. Part I. Oxidation of 2,6-Di-tert-butyl-anilines to Radical Cations: General Considerations, Electroanalytical Experiments and Spectroscopy.
  16. B. Speiser, A. Rieker und S. Pons, J. Electroanal. Chem. 159, 63 - 88 (1983); Electrochemistry of Anilines. Part II. Oxidation to Dications, Electrochemical and UV/VIS Spectroelectrochemical Investigation.
  17. J.F. Cassidy, S. Pons, A.S. Hinman und B. Speiser, Can. J. Chem. 62, 716 - 720 (1984); Simulation of Edge Effects in Electroanalytical Experiments by Orthogonal Collocation. Part 4. Application to Voltammetric Experiments.
  18. B. Speiser, J. Electroanal. Chem. 171, 95 - 109 (1984); Electroanalytical Investigations. Part V. The Simulation of Fast Chemical Reactions in Cyclic Voltammetry by a Combination of the Orthogonal Collocation Method and the Heterogeneous Equivalent Approach.
  19. B. Speiser, Anal. Chem. 57, 1390 - 1397 (1985); Multiparameter Estimation: Extraction of Information from Cyclic Voltammograms.
  20. P. Hertl, A. Rieker und B. Speiser, J. Electroanal. Chem. 200, 147 - 158 (1986); Electrochemistry of Anilines. Part III. Electrochemical Oxidation of Sterically Hindered 4-Aminobiphenyls and Correlation of Formal Potentials with Hammett $\sigma$ Values.
  21. P. Hertl und B. Speiser, J. Electroanal. Chem. 217, 225 - 238 (1987); Electroanalytical Investigations. Part VI. The Simulation of Fast Chemical Equilibrium Reactions in Cyclic Voltammetric Reaction-Diffusion Models with Spline Collocation.
  22. P. Hertl und B. Speiser, J. Electroanal. Chem. 235, 57 - 70 (1987); Electroanalytical Investigations. Part VII. The Simulation of Fast Chemical Equilibrium Reactions in Cyclic Voltammetric Reaction-Diffusion Models with a Combination of the Heterogeneous Equivalent Technique and Orthogonal Collocation.
  23. P. Urban und B. Speiser, J. Electroanal. Chem. 241, 17 - 31 (1988); Electroanalytical Investigations. Part VIII. The Use of an Expanding Simulation Space in the Simulation of Electrochemical Reaction-Diffusion Models with Orthogonal Collocation.
  24. P. Hertl und B. Speiser, J. Electroanal. Chem. 250, 237 - 256 (1988); Electroanalytical Simulations. Part IX - The Simulation of a Second-Order Chemical Reaction Preceding a Reversible Electron Transfer under Cyclic Voltammetric Conditions Using Orthogonal Collocation.
  25. B. Scharbert und B. Speiser, J. Chemomet. 3, 61 - 80 (1988); Chemical Information from Electroanalytical Data. Part 1. Determination of System Parameters for Quasi-Reversible Electron Transfer Reactions from Cyclic Voltammetric Test Data and Data for the Reduction of Cerium(IV)bis(octaethylporphyrinate).
  26. A. Dettling, A. Rieker und B. Speiser, Tetrahedron Lett. 29, 4533 - 4534 (1988); Reversible Electrochemical Oxidation of 2,5,8,11-Tetra-tert-butyl-peri-xanthenoxanthene to its Radical Cation and Dication.
  27. B. Speiser in G. Gauglitz (Hrsg.), Softwareentwicklung in der Chemie, Band 3, Springer, Berlin, 1989, S. 321 - 332; EASIEST - A Program System for Electroanalytical Simulation and Parameter Estimation. Part 2. EASIEST - ein Programmsystem zur Simulation von und Parameterbestimmung aus elektroanalytischen Experimenten.
  28. B. Speiser und A. Rieker, Nachr. Chem. Tech. Lab. 37, 616 - 618 (1989); Energie durch elektrochemisch induzierte Kernfusion?
  29. B. Speiser, Comput. Chem., 14, 127 - 140 (1990); EASIEST - A Program System for Electroanalytical Simulation and Parameter Estimation. Part 1. Simulation of Cyclic Voltammetric and Chronoamperometric Experiments.
  30. B. Speiser in J. Gasteiger (Hrsg.), Software Development in Chemistry 4, Springer, Berlin, 1990, S. 321 - 330; Electroanalytical Simulations. Part 10. The Simulation of Fast Second Order Reactions in Electrochemical Systems.
  31. A. Rieker und B. Speiser, Tetrahedron Lett. 31, 5013 - 5014 (1990); Electrochemistry of Anilines. Part 5. Spectroscopic and Electrochemical Characterization of a Persistent Biphenylyl Nitrenium Ion.
  32. B. Speiser, Trends in Anal. Chem., 10, 9 - 11 (1991); EASIEST - A Program System for Electroanalytical Simulation and Parameter Estimation. Part 3. Second-order Catalytic Electrode Reactions at Amperometric Biosensors. The Application of Polynomial and B-Spline Interpolation to the Description of Cyclic Voltammetric Features.
  33. B. Speiser, Anal. Chim. Acta, 243, 301 - 310 (1991); Electroanalytical Simulations. Part 11. Orthogonal Collocation Simulation of Fast Second-order Chemical Reactions Coupled to an Electron Transfer with a Heterogeneous Equivalent Formulation.
  34. B. Speiser, J. Electroanal. Chem., 301, 15 - 35 (1991); Chemical Information from Electroanalytical Data. Part 2. Determination of Rate and Equilibrium Constants of a Chemical Reaction Preceding a Reversible Electron Transfer from Cyclic Voltammetric Data; Erratum: J. Electroanal. Chem. 306, 313 (1991).
  35. P. Hertl, A. Rieker und B. Speiser, J. Electroanal. Chem., 301, 37 - 52 (1991); Electrochemistry of Anilines. Part 4. Determination of Rate and Equilibrium Constants for the Protonation of 2,6-Di-tert-butyl-4-(4$^\prime$-R-phenyl)-anilines in Acetonitrile from Cyclic Voltammetric Data. Erratum: J. Electroanal. Chem. 306, 313 (1991).
  36. B. Speiser, A. Leverenz und M. Hanack, Synth. Met., 41 - 43, 2979 - 2982 (1991); The Mechanism of Na[PcCo(CN)$_2$] Electrocrystallization -- Analysis of Adsorption Phenomena by a Comparison of Simulated and Experimental Cyclic Voltammograms.
  37. A. Nishinaga, K. Tajima, B. Speiser, E. Eichhorn, A. Rieker, H. Ohya-Nishiguchi und K. Ishizu, Chem. Lett. 1991, 1403 - 1406; Substituent Effects on the Formal Potential of the Co(II)/Co(III) Redox Couple for Co(salen) Derivatives.
  38. B. Speiser and A. Rieker, J. Org. Chem., 56, 4664 - 4671 (1991); Electrochemistry of Anilines. Part 6. Reactions of Electrogenerated Biphenylyl Nitrenium Ions.
  39. A. Rieker, B. Speiser, K.-M. Mangold und M. Hanack, Z. Naturforsch., 46b, 1125 - 1126 (1991); Potential Error Sources in Combined Electrochemistry/Neutron Detection Experiments.
  40. U. Löffler, B. Speiser und W. Göpel, Electroanalysis, 3, 917 - 923 (1991); The Determination of Electron Transfer Parameters for Monosubstituted Ferrocenes Suitable as Mediators in Amperometric Biosensors.
  41. A. Leverenz und B. Speiser, J. Electroanal. Chem., 318, 69 - 89 (1991); Electroanalytical Simulations. Part 13. The Simulation of Adsorption Processes at an Electrode by Orthogonal Collocation Algorithms.
  42. E. Eichhorn, A. Rieker und B. Speiser, Anal. Chim. Acta, 256, 243 - 249 (1992); Numerical Method to Correct $iR$ Drop Errors in Cyclic Voltammetric Potential Data for (Quasi)Reversible Electrode Processes.
  43. B. Gollas und B. Speiser, Angew. Chem., 104, 336 - 338 (1992); Angew. Chem. Int. Ed. Engl., 31, 332 - 334 (1992); Elektrochemie von Triazenen. Teil 1. Elektrochemische Oxidation von 1-p-Dimethylaminophenyl-3,3-dimethyltriazen -- Cyclovoltammetrischer Nachweis eines Triazen-Radikalkations und -Dikations.
  44. A. Rieker, P. Hertl und B. Speiser, in R. Louw und P. Mulder (Hrsg.), Proc. Sixth Int. Symp. Org. Free Rad., Noordwijkerhout, Niederlande, 1992, S. 256 - 259 (ISBN: 90-9004445-0); Persistent Radicals Derived from Primary Anilines.
  45. A. Leverenz, B. Speiser und M. Hanack, J. Electroanal. Chem., 323, 275 - 287 (1992); Cyclic Voltammetry of Na[PcCo(CN)$_2$] -- Analysis of Adsorption Phenomena During Electrooxidation.
  46. A. Rieker, B. Speiser und H. Straub, DECHEMA-Monographien, Band 125, 777 - 782 (1992); Reaktionen anodisch erzeugter Phenoxeniumionen mit Nucleophilen.
  47. A. Nishinaga, S. Förster, A. Rieker, E. Eichhorn und B. Speiser, Tetrahedron Lett. 33, 4425 - 4428 (1992); Co(salen) Catalyzed Oxidation of 2,4,6-Trisubstituted Anilines with t-butyl Hydroperoxide.
  48. B. Speiser und H. Stahl, Tetrahedron Lett. 33, 4429 - 4432 (1992); Electrochemistry of Triazenes. Part 2. Formation of the 2,7-Dimethoxy-5,10-dimethyl-5,10-dihydrophenazine Radical Cation during Oxidation of 1,3-Diaryl-3-methyltriazenes.
  49. E. Eichhorn, A. Rieker und B. Speiser, Angew. Chem., 104, 1246 - 1248 (1992); Angew. Chem. Int. Ed., 31, 1215 - 1217 (1992); Elektrochemie von Oxygenierungskatalysatoren. Teil 1. Die elektrochemische Oxidation von N,N$^\prime$-Bis(salicyliden)ethylendiiminato-kobalt(II) in Lösungsmittelgemischen -- Ein Beispiel für ein Leiterschema mit gekoppelten Elektronentransfer- und Lösungsmittelaustauschreaktionen.
  50. E. Eichhorn, A. Rieker, B. Speiser, J. Sieglen und J. Strähle, Z. Naturforsch., 48b, 418 - 424 (1993); Electrochemistry of Oxygenation Catalysts. Part 2. Improved Synthesis, Crystal Structure, and Electrochemical Properties of N,N$^\prime$-Bis(salicyliden)-ethylenediaminato Cobalt(III) Chloride.
  51. C. Schulz und B. Speiser, J. Electroanal. Chem., 354, 255 - 271 (1993); Electroanalytical Simulations. Part 14. Simulation of Frumkin-Type Adsorption Processes by Orthogonal Collocation under Cyclic Voltammetric Conditions.
  52. B. Speiser, Acta Chem. Scand., 47, 1238 -1240 (1993); Electrochemical Simulations. Part 15. Advanced Orthogonal Collocation Techniques in Problem Situations of the EC$_{\rm cat}$ Mechanism. A Comment on the Paper ,,Efficiency of Electrochemical Kinetic Simulations by Orthogonal Collocation and Finite Difference Methods. A Comparison`` by L.K. Bieniasz and D. Britz.
  53. T. Vering, W. Schuhmann, D. Seiwald, H.-L. Schmidt, B. Speiser und L. Ye, J. Electroanal. Chem., 364, 277 - 279 (1994); A New Multipuls-Method for Potentiometric Measurements of Enzymatic Redox Reactions.
  54. E. Eichhorn und B. Speiser, J. Electroanal. Chem., 365, 207 - 212 (1994); Electrochemistry of Oxygenation Catalysts. Part 4. Solvent Composition Dependent Isopotential Points in Cyclic Voltammograms of Co(salen)$^+$.
  55. B. Gollas, B. Krauß, B. Speiser und H. Stahl, Curr. Sep., 13, 42 - 44 (1994); Design of a Single-Unit Haber-Luggin Capillary/Dual Reference-Electrode System.
  56. L. Dunsch, B. Gollas, A. Neudeck, A. Petr, B. Speiser und H. Stahl, Chem. Ber., 127, 2423 - 2429 (1994); Electrochemistry of Triazenes. Part 3. One-Electron Oxidation of Aryltriazenes to Radical Cations.
  57. E. Eichhorn, A. Rieker, B. Speiser und H. Stahl, in S. Torii (Hrsg.), Novel Trends in Electroorganic Synthesis, Proc. 2$^{\rm nd}$ Intl. Symp. on Electroorg. Synth., Kodansha, Tokyo, 1994 (Publ. 1995), S. 173 - 174 (ISBN: 4-06-207503-2); Electrochemical Investigation of Oxygenation Catalysts.
  58. B. Speiser und H. Stahl, Angew. Chem., 107, 1222 - 1224 (1995); Angew. Chem. Int. Ed., 34, 1086 - 1089 (1995); Elektrochemie von Oxygenierungskatalysatoren. 5. Mitteilung. Komplexierung von [N,N$^\prime$-Bis(salicyliden)ethylendiiminato]cobalt(III) durch Aniline in Dimethylformamid.
  59. X. Wei und B. Speiser, Electrochim. Acta, 40, 2477 - 2482 (1995); Electrochemistry of Triazenes. Part 4. Reaction of Diazonium Ions Generated Electrochemically from 1-Aryl-3,3-dimethyltriazenes in Acetonitrile.
  60. B. Gollas, B. Speiser, J. Sieglen und J. Strähle, Organometallics, 15, 260 - 271 (1996); Electrochemistry of Ruthenium Metallocenes. 1. Synthesis, NMR, and Anodic Electrochemical Behavior of Vinyl-Substituted Ruthenium Cyclophane Complexes.
  61. G. Frenking, A. Rieker, J. Salbeck und B. Speiser, Z. Naturforsch., 51b, 377 - 380 (1996); 2,5,8,11-Tetra-tert-butyl-peri-xanthenoxanthene and its Dication -- Spectroelectrochemistry and Model Calculations on a Dioxa-22-$\pi$-system.
  62. B. Gollas, B. Speiser, H. Stahl, J. Sieglen und J. Strähle, Z. Naturforsch., 51b, 388 - 398 (1996); Electrochemistry of Oxygenation Catalysts. Part 6. Electrosynthesis, Structure, Analytical, and Electrochemical Properties of Monomeric [Co$^{\rm
III}$(salen)(DMF)$_2$]$^+$ X$^-$ Salts (X = PF$_6$, ClO$_4$).
  63. X. Wei und B. Speiser, Electrochim. Acta, 42, 73 - 79 (1997); Ring Formation from 2-Arylazo-3-aminocrotononitriles to 1,2,3[2H]-triazole-4-carbonitriles and Pyrazoles by Anodic Oxidation.
  64. B. Speiser, J. Electroanal. Chem., 413, 67 - 79 (1996); Electroanalytical Simulations. Part 16. Simulation of Controlled Current Bulk Electrolysis Experiments by Orthogonal Collocation: General Model and Simple Charge Transfer Mechanisms.
  65. B. Speiser, Angew. Chem., 108, 2623 - 2626 (1996); Angew. Chem. Intl. Ed. Engl. 35, 2471 - 2474 (1996); Elektronentransfer und chemische Reaktion: schrittweise oder konzertiert? -- Zur Konkurrenz von nucleophiler Substitution und Elektronenübertragung.
  66. M. Hecht, F.A. Schultz und B. Speiser, Inorg. Chem., 35, 5555 - 5563 (1996); Ligand Structural Effects on the Electrochemistry of Chromium(III) Aminocarboxylate Complexes.
  67. B. Gollas und B. Speiser, in F. Beck (Hrsg.), Elektrochemie der Elektronenleiter. Metalle - Oxide - Polymere, Beiträge der Jahrestagung der GDCh-Fachgruppe Angewandte Elektrochemie, GDCh-Monographie, Band 3, Gesellschaft Deutscher Chemiker, Frankfurt, 1996, S. 580 (ISBN: 3-924763-56-9); Elektrochemische Redoxreaktionen von Rutheniumkomplexen aromatischer Liganden: Redoxpolymerfilme aus Vinylcyclophan-Ruthenium-Metallocenen.
  68. S. Dümmling, E. Eichhorn, S. Schneider, B. Speiser und M. Würde, Curr. Sep., 15, 53 - 56 (1996); Recycling of the Supporting Electrolyte Tetra(n-butyl)ammonium Hexafluorophosphate from Used Electrolyte Solutions.
  69. E. Eichhorn, A. Rieker und B. Speiser, Z. anorg. allg. Chem., 623, 810 - 817 (1997); Elektrochemie von Oxygenierungskatalysatoren. Teil 7. Synthese und Elektrochemie von Komplexen des Co(salen)-Typs mit zwei potentiellen über Spacer angebundenen axialen basischen Liganden.
  70. B. Gollas, B. Speiser, J. Sieglen, J. Strähle und C. Maichle-Mössmer, Z. Krist., 212, 269 - 270 (1997); Crystal Structure of Bis(biphenyl)chromium(I)iodide Chloroform Solvate, [(C$_{12}$H$_{10}$)$_2$CrI] $\times$ CHCl$_3$.
  71. B. Gollas, B. Speiser, J. Sieglen, J. Strähle und C. Maichle-Mössmer, Z. Krist., 212, 271 - 272 (1997); Crystal Structure of E-4-(2$^\prime$-Ethoxycarbonyl-2$^\prime$-methyl)-ethenyl-[2$_2$]paracyclophane, C$_{22}$H$_{24}$O$_2$.
  72. E. Eichhorn, A. Rieker, B. Speiser und H. Stahl, Inorg. Chem., 36, 3307 - 3317 (1997); Electrochemistry of Oxygenation Catalysts. Part 3. Thermodynamic Characterization of Electron Transfer and Solvent Exchange Reactions of Co(salen)/[Co(salen)]$^+$ in DMF, Pyridine and Their Mixtures.

  73. B. Gollas, I. Hesse, R. Lotz, H. Pasch, B. Speiser und I. Zagos, Liebigs. Ann./Recueil, 1997, 2255 - 2264; Electrochemical Oxidation of 4-Ethenyl-[$2_2$]paracyclophane: Cyclic Voltammetry, Electrosynthesis of Polymers, Analysis by Liquid Chromatography and Mass Spectrometry.
  74. N. Kuhn, G. Weyers, S. Dümmling, und B. Speiser, Phosphorus, Sulfur, and Silicon 128, 45 - 62 (1997); Derivate des Imidazols. 25. Reduktion von Carben-Addukten des Kohlenstoffdisulfids: ein neuer Weg zu elektronenreichen 1,1-Dithiolaten.
  75. B. Speiser, M. Würde und C. Maichle-Mössmer, Chem. Eur. J., 4, 222 - 233 (1998); Electrochemistry of Polyaminobenzenes, Part 1. Electrochemical Oxidation of Hexakis(dimethylamino)benzene.
  76. L.K. Bieniasz und B. Speiser, J. Electroanal. Chem., 441, 271 - 285 (1998); Use of Sensitivity Analysis Methods in the Modelling of Electrochemical Transients. Part 1. Gaining More Insight into the Behaviour of Kinetic Models. Erratum: J. Electroanal. Chem., 452, 139 (1998);
  77. L.K. Bieniasz, S. Dümmling, B. Speiser und M. Würde, J. Electroanal. Chem., 447, 173 - 186 (1998); Use of Sensitivity Analysis Methods in the Modelling of Electrochemical Transients. Part 2. Model Expansion and Model Reduction.
  78. L.K. Bieniasz und B. Speiser, J. Electroanal. Chem., 458, 209 - 229 (1998); Use of Sensitivity Analysis Methods in the Modelling of Electrochemical Transients. Part 3. Statistical Error/Uncertainty Propagation in Simulation and in Nonlinear Least-Squares Parameter Estimation.
  79. E. Lindner, I. Krebs, R. Fawzi, M. Steimann und B. Speiser, Organometallics, 18, 480 - 489 (1999); Preparation, Properties, and Reactions of Metal-Containing Heterocycles. Part 98. Synthesis, Structure, and Electrochemistry of Osmametallocenophanes with Different Ring Size.
  80. B. Speiser, Curr. Org. Chem., 3, 171 - 191 (1999); From Cyclic Voltammetry to Scanning Electrochemical Microscopy: Modern Electroanalytical Methods to Study Organic Compounds, Materials, and Reactions.
  81. B. Speiser und S. Dümmling, in J. Russow, G. Sandstede und R. Staab (Hrsg.), GDCH-Monographien, Band 14, 33 - 39 (1999); Zweielektronentransfer-Redoxsysteme. Teil 1. Cyclovoltammetrische Charakterisierung von Zweielektronentransfers an organischen und metallorganischen Molekülen. (gleichzeitig: Electrochemie von Rutheniummetallocenen, Teil 2)
  82. B. Speiser, C. Tittel, W. Einholz und R. Schäfer, J. Chem. Soc., Dalton Trans., 1999, 1741 - 1751; Two-Electron-Transfer Redox Systems. Part 2. Redox Reactions of the Boron Subhalide Clusters B$_n$Cl $_n^{0/\bullet-/2-}$ ($n=8,9$) Investigated by Electrochemical and Spectroscopic Methods.
  83. S. Dümmling, B. Speiser, N. Kuhn und G. Weyers, Acta Chem. Scand., 53, 876 - 886 (1999); Two-Electron-Transfer Redox Systems. Part 3. Electrochemical Reduction of N,N$^\prime$-Dialkyl-4,5-dimethylimidazolium-2-dithiocarboxylates to 1,1-Dithiolate Anions in THF. Steric Modulation of Potential Ordering by Substituents.
  84. M.P. Feth, U. Reinöhl, T.S. Ertl, M. Seiler, H. Bertagnolli, S. Maier, B. Speiser und H.A. Mayer, HASYLAB Ann. Rep. 780 - 781 (1999); EXAFS Investigation of Organometallic Iridium Complexes.
  85. B. Speiser, M. Würde und M.G. Quintanilla, Electrochem. Commun., 2, 65 - 68 (2000); Electrochemistry of Polyaminobenzenes. Part 2. Oxidation of Hexakis(dimethylamino)benzene at High Potentials.
  86. N. Kuhn, H. Kotowski, M. Steimann, B. Speiser, M. Würde und G. Henkel, J. Chem. Soc., Perkin Trans. 2, 2000, 353 - 363; Synthesis, Oxidation and Protonation of Octamethyl-1,1$^\prime$-bipyrrole.
  87. B. Gollas, B. Speiser, I. Zagos und C. Maichle-Mössmer, J. Organomet. Chem., 602, 75 - 90 (2000); Electrochemistry of Ruthenium Metallocenes. Part 3. Synthesis, Spectroscopic Characterization, and Electrochemical Redox Reactions of Ruthenium Arene Complexes with Methacrylic Acid and Methacrylate Ester Substituted Cyclophane Ligands.
  88. J.J. Wolff, A. Zietsch, B. Nuber, F. Gredel, B. Speiser und M. Würde, J. Org. Chem., 66, 2769 - 2777 (2001); Electrochemistry of Polyaminobenzenes. Part 3. Hexaaminobenzene Derivatives: Synthesis and Unusual Oxidation Behavior.
  89. S. Buchmann, H.A. Mayer, B. Speiser, M. Seiler, H. Bertagnolli, S. Steinbrecher und E. Plies, Electrochim. Acta, 46, 3207 - 3217 (2001); Electrochemistry of Transition Metal Complex Catalysts. Part 8. One-Electron Oxidation of an Iridium Complex with a Cyclohexane-Derived Tripod Phosphine Ligand -- Cyclic Voltammetry and Preparative Electrolysis.
  90. B. Speiser, K. Ludwig, A. Stauß und M.G. Quintanilla, Proc. Electrochem. Soc., 2001-14, 69 - 72 (2001); Two-Electron-Transfer Redox Systems. Part 4. Electrochemical Oxidation of Hexa(benzylthio)benzene -- Formation and Reaction of a Radical Cation.
  91. B. Speiser, W. Märkle und S. Heiß, in J. Russow und H.J. Schäfer, GDCH-Monographie, Band 23, Elektronenübertragung in Chemie und Biochemie, S. 285 - 292 (2001); Anodische Oxidation von Benzaldehydphenylhydrazonen in Gegenwart von Nitrilen
  92. W. Einholz, K. Vaas, C. Wieloch, B. Speiser, T. Wizemann, M. Ströbele und H.-J. Meyer, Z. anorg. allgem. Chem., 628, 258 - 268 (2002); Zweielektronentransfer-Redoxsysteme, Teil 5. Chemische und cyclovoltammetrische Untersuchung der Redoxreaktionen der Decahalogendecaborate closo-[B$_{10}$X$_{10}]^{2-}$ und hypercloso-[B$_{10}$X $_{10}]^{\bullet-}$ (X = Cl, Br). Kristallstrukturanalyse von Cs$_2$[B$_{10}$Br$_{10}$] $\cdot$ 2 H$_2$O.
  93. B. Speiser, Anal. Bioanal. Chem., 372, 29 - 30 (2002); Molecular Electrochemistry.
  94. K. Ludwig und B. Speiser, J. Electroanal. Chem. 531, 1 - 8 (2002); Electroanalytical Simulations, Part 17. Calculation of Open Circuit Potentials during Fractional Electrolysis in Two-Electron-Transfer Systems.
  95. K. Ludwig, M.G. Quintanilla, B. Speiser und A. Stauß, J. Electroanal. Chem. 531, 9 - 18 (2002); Two-Electron-Transfer Redox Systems. Part 6. Two-Electron Oxidation of Hexakis(benzylthio)benzene -- A Study by Electrolysis and Cyclic Voltammetry.
  96. H.A.Y. Mohammad, J.C. Grimm, K. Eichele, H.-G. Mack, B. Speiser, F. Novak, M.G. Quintanilla, W.C. Kaska und H.A. Mayer, Organometallics 21, 5775 - 5784 (2002); C-H Oxidative Addition with a (PCP)Ir$^{\rm
III}$-Pincer-Complex.
  97. B. Speiser, T. Wizemann und M. Würde, Inorg. Chem., 42, 4018 - 4028 (2003); Two-Electron-Transfer Redox Systems. Part 7. Two-Step Electrochemical Oxidation of the Boron Subhalide Cluster Dianions B$_6$X$_6^{2-}$ (X = Cl, Br, I)
  98. S. Buchmann, H.A. Mayer, B. Speiser, M. Seiler, M.P. Feth, H. Bertagnolli, S. Steinbrecher und E. Plies, Electrochim. Acta, 48, 2725 - 2737 (2003); Electrochemistry of Transition Metal Complex Catalysts. Part 9. One- and Two-Electron Oxidation of Iridium Complexes with Cyclohexane-Derived Tripod Phosphine Ligands; Erratum: Electrochim. Acta, 48, 4319 - 4320 (2003).
  99. F. Novak, B. Speiser, E. Lindner, Z.-L. Lu und H.A. Mayer, Angew. Chem., 116, 2059 - 2062 (2004); Elektrochemie von Übergangsmetallkatalysatoren. Teil 11. Eine chemisch modifizierte Platinelektrode als zweizähniger Diaminligand zur Bildung wohldefinierter immobilisierter Bis($\eta^1$-P-ether-phosphan)(diamin)ruthenium(II)-Komplexe; Angew. Chem. Int. Ed. 43, 2025 - 2028 (2004); Electrochemistry of Transition Metal Complex Catalysts. Part 11. A Chemically Modified Platinum Electrode as a Bidentate Diamine Ligand for Forming Well-Defined, Immobilized Bis($\eta^1$-P-ether-phosphane)(diamine)ruthenium(II) Complexes; Berichtigung: Angew. Chem., 116, 2934 (2004).

  100. B. Schetter und B. Speiser, J. Organomet. Chem., 689, 1472 - 1480 (2004); Reaction of Ferrocenecarboxylic Acid With N,N$^\prime$-Disubstituted Carbodiimides. Synthesis, Spectroscopic and X-ray Crystallographic Analysis of N,N$^\prime$-Disubstituted N-Ferrocenoylureas and Identification of a One-Pot Coupling Reagent for the Formation of Ferrocenecarboxamides in a Non-Aqueous Solvent; Erratum: J. Organomet. Chem., 689, 2743 (2004);
  101. K. Ludwig, L. Rajendran und B. Speiser, J. Electroanal. Chem., 568, 203 - 214 (2004); EChem++ - An Object Oriented Problem Solving Environment for Electrochemistry. Part 1. A C++ Class Collection for Electrochemical Excitation Functions; Erratum: J. Electroanal. Chem., 571, 119 (2004).
  102. F. Novak, B. Speiser, H.A.Y. Mohammad und H.A. Mayer, Electrochim. Acta, 49, 3841 - 3853 (2004); Electrochemistry of Transition Metal Complex Catalysts. Part 10. Intra- and Intermolecular Electrochemically Activated C-H Addition to the Central Metal Atom of a P-C-P-Pincer Iridium Complex.
  103. K. Ludwig und B. Speiser, J. Chem. Inf. Comput. Sci., 44, 2051 - 2060 (2004); EChem++ - An Object-Oriented Problem Solving Environment for Electrochemistry. 2. The Kinetic Facilities of Ecco - A Compiler for (Electro-)Chemistry; Erratum: J. Chem. Inf. Comput. Sci., 46, 2762 (2006).
  104. W. Märkle, B. Speiser, C. Tittel und M. Vollmer, Electrochim. Acta, 50, 2753 - 2762 (2005); Combinatorial Micro Electrochemistry. Part 1. Automated Micro Electrosynthesis of Iminoquinol Ether and [1,2,4]Triazolo[4,3-a]pyridinium Perchlorate Collections in the Wells of Microtiter Plates.
  105. T. Erichsen, S. Reiter, W. Märkle, C. Tittel, V. Ryabova, E.M. Bonsen, G. Jung, B. Speiser und W. Schuhmann, Rev. Sci. Instrum., 76, 062204-1 - 062204-11 (2005); Combinatorial Micro Electrochemistry. Part 2. Development and Evaluation of an Electrochemical Robotic System.
  106. W. Märkle und B. Speiser, Electrochim. Acta, 50, 4916 - 4925 (2005); Combinatorial Microelectrochemistry. Part 3. On-line Monitoring of Electrolyses by Steady-State Cyclic Voltammetry at Microelectrodes.
  107. E. Lindner, Z.-L. Lu, H.A. Mayer, B. Speiser, C. Tittel und I. Warad, Electrochem. Commun., 7, 1013 - 1020 (2005); Combinatorial Micro Electrochemistry. Part 4. Cyclic Voltammetric Redox Screening of Homogeneous Ruthenium(II) Hydrogenation Catalysts (also: Electrochemistry of Transition Metal Complexes, Part 12).
  108. E.P. Sapozhnikova, M. Bogdan, B. Speiser, und W. Rosenstiel, J. Electroanal. Chem., 588, 15 - 26 (2006); EChem++ - An Object-Oriented Problem Solving Environment for Electrochemistry. Part 3. Classification of Voltammetric Signals by the Fuzzy ARTMAP Neural Network with Respect to Reaction Mechanisms.
  109. K. Ludwig und B. Speiser, J. Electroanal. Chem., 588, 74 - 87 (2006); EChem++ - An Object Oriented Problem Solving Environment for Electrochemistry: Part 4. Adaptive Multilevel Finite Elements Applied to Electrochemical Models. Algorithm and Benchmark Calculations.
  110. S. Eisele, M. Schwarz, B. Speiser und C. Tittel, Electrochim. Acta, 51, 5304 - 5306 (2006); Diffusion Coefficient of Ferrocene in 1-Butyl-3-methylimidazolium Tetrafluoroborate -- Concentration Dependence and Solvent Purity.
  111. A. Budny, F. Novak, N. Plumeré, B. Schetter, B. Speiser, D. Straub, H.A. Mayer und M. Reginek, Langmuir, 22, 10605 - 10611 (2006); Redox-Active Silica Nanoparticles. Part 1. Electrochemistry and Catalytic Activity of Spherical, Nonporous Silica Particles with Nanometric Diameters and Covalently Bound Redox-active Modifications (auch: Electrochemistry of Transition Metal Complexes, Part 13).
  112. K. Ludwig und B. Speiser, J. Electroanal. Chem., 608, 91 - 101 (2007); EChem++ - An Object Oriented Problem Solving Environment for Electrochemistry. Part 5. A Differential-Algebraic Approach to the Error Control of Adaptive Algorithms.
  113. K. Ludwig, I. Morales und B. Speiser, J. Electroanal. Chem., 608, 102 - 110 (2007); EChem++ - An Object Oriented Problem Solving Environment for Electrochemistry. Part 6. Adaptive Finite Element Simulations of Controlled-Current Electrochemical Experiments
  114. N. Plumeré und B. Speiser, Electrochim. Acta, 53, 1244 - 1251 (2007); Redox-Active Silica Nanoparticles. Part 2. Photochemical Hydrosilylation on a Hydride Modified Silica Particle Surface for the Covalent Immobilization of Ferrocene.
  115. N. Plumeré, B. Speiser, H. A. Mayer, D. Joosten, and L. Wesemann, Chem. Eur. J., 15, 936 - 946 (2009). Redox-Active Silica Nanoparticles, Part 3. High-Temperature Chlorination-Reduction Sequence for the Preparation of Silicon Hydride Modified Silica Surfaces.
  116. M. Schwarz und B. Speiser, Electrochim. Acta, 54, 3735 - 3744 (2009); Combinatorial Micro-Electrochemistry. Part 5. Electrosynthesis Screening of the Electroreductive Coupling of $\alpha$,$\beta$-Unsaturated Esters and Allyl Bromides in a Room Temperature Ionic Liquid.
  117. N. Plumeré, B. Speiser, B. Dietrich, K. Albert, J.J. Pesek und M.T. Matyska, Langmuir, 25, 13481 - 13487 (2009); Thermally Induced Radical Hydrosilylation for Synthesis of C18 HPLC Phases from Highly Condensed Si-H Terminated Silica Surfaces.
  118. F. Novak, N. Plumeré, B. Schetter, B. Speiser, D. Straub, H.A. Mayer, M. Reginek, K. Albert, G. Fischer, C. Meyer, H.-J. Egelhaaf and B. Børresen, J. Solid State Electrochem., 14, 289 - 303 (2010); Redox-active Silica Nanoparticles. Part 4. Synthesis, Size Distribution, and Electrochemical Adsorption Behavior of Ferrocene- and (Diamine)(diphosphine)-ruthenium(II)-modified Stöber Silica Colloidal Particles.
  119. J. Janisch, A. Ruff, B. Speiser, C. Wolff, J. Zigelli, S. Benthin, V. Feldmann und H.A. Mayer, J. Solid State Electrochem., 15, 2083 - 2094 (2011); on-line-Version: DOI 10.1007/s10008-011-1399-3; Consistent Diffusion Coefficients of Ferrocene in some Non-Aqueous Solvents: Electrochemical Simultaneous Determination together with Electrode Sizes and Comparison to Pulse Gradient Spin Echo NMR Results.
  120. N. Plumeré, A. Ruff, B. Speiser, V. Feldmann und H.A. Mayer, J. Colloid Interface Sci., 368, 208 - 219 (2012); on-line-Version: DOI 10.1016/j.jcis.2011.10.070; Redox-active Silica Nanoparticles. Part 5. Stöber Silica Particles as Basis for Redox-active Modifications -- Particle Shape, Size, Polydispersity and Porosity.
  121. J. Schäfer, M. Scheurer, B. Speiser, W. Kuznik und I.V. Kityk, Spectrochim. Acta A, 95, 193 - 98 (2012); on-line-Version: http://dx.doi.org/10.1016/j.saa.2012.04.039; Electrochemistry and DFT Simulation of Optical Spectra for N-Ferrocenoyl-N$^\prime$-$\omega$-decenoyl-ethylenediamine.
  122. S. Benthin und B. Speiser, J. Electroanal. Chem., 682, 147 - 157 (2012); online-Version: http://dx.doi.org/10.1016/j.jelechem.2012.07.024; EChem++ - An Object Oriented Problem Solving Environment for Electrochemistry. Part 7. Simulation of Equilibrium Electron Transfer Processes with Implicit Dirichlet Boundary Conditions.
  123. S. Biswas, M. Müller, C. Tönshoff, K. Eichele, C. Maichle-Mössmer, A. Ruff, B. Speiser und H.F. Bettinger, Eur. J. Org. Chem., 4634 - 4639 (2012); online-Version: DOI: 10.1002/ejoc.201200322; The Overcrowded Borazine Derivative of Hexabenzotriphenylene via Dehydrohalogenation.

Buchkapitel

  1. B. Speiser in A.J. Bard und I. Rubinstein (Hrsg.), Electroanalytical Chemistry, Vol. 19, Simulation of Electroanalytical Experiments by Numerical Methods -- Recent Advances, Marcel Dekker, New York, 1996, S. 1 - 108.
  2. B. Speiser, Elektroanalytische Methoden, in K.E. Geckeler und H. Eckstein (Hrsg.), Bioanalytische und biochemische Labormethoden, Vieweg, Braunschweig/Wiesbaden, 1998, S. 301 - 370.
  3. B. Speiser, in A.J. Bard und M. Stratmann (Hrsg.), Encyclopedia of Electrochemistry, Vol. 3 Instrumentation and Electroanalytical Chemistry (Bandherausgeber: P. Unwin), Kapitel 2.1: Linear Sweep and Cyclic Voltammetry, Wiley-VCH, Weinheim, 2003, S. 81 - 104.
  4. B. Speiser, in R. Gleiter und H. Hopf (Hrsg.), Modern Cyclophane Chemistry, Wiley-VCH, Weinheim, 2004, Kapitel 14, Molecular Electrochemistry of Cyclophanes, S. 359 - 379.
  5. B. Speiser, in A.J. Bard und M. Stratmann (Hrsg.), Encyclopedia of Electrochemistry, Vol. 8 Organic Electrochemistry (Bandherausgeber: H.J. Schäfer), Kapitel 1: Methods to Investigate Mechanisms of Electroorganic Reactions, Wiley-VCH, Weinheim, 2004, S. 1 - 23.
  6. H.A.Y. Mohammad, J.C. Grimm, K. Eichele, H.-G. Mack, B. Speiser, F. Novak, W.C. Kaska und H. A. Mayer, Double Cyclometalation: Implications for C-H Oxidative Addition With PCP Pincer Compounds of Iridium, in K.I. Goldberg und A.S. Goldman (Eds.), ,,Activation and Functionalization of C-H Bonds``, ACS Symposium Series, American Chemical Society, No. 885, Kapitel 14, S. 234 - 247 (2004).
  7. B. Speiser, in R.F. Savinell, K.-i. Ota und G. Kreysa (Hrsg.), Encyclopedia of Applied Electrochemistry, SpringerReference, Springer, Heidelberg; online-Version: DOI 10.1007/SpringerReference-303485 2012-06-15 18:14:24 UTC Numerical Simulations in Electrochemistry.

Buchbesprechungen

  1. B. Speiser, Angew. Chem., 105, 1273 - 1274 (1993); Angew. Chem. Intl. Ed. Engl. 32, 1218 - 1219 (1993); ,,Electron and Proton Transfer in Chemistry and Biology``, herausgegeben von A. Müller, H. Ratajczak, W. Junge und E. Diemann.
  2. B. Speiser, J. Electroanal. Chem., 374, 280 - 282 (1994); ,,Cyclic Voltammetry. Simulation and Analysis of Reaction Mechanisms``, von D.K. Gosser Jr.
  3. B. Speiser, Angew. Chem., 108, 853 - 854 (1996); ,,Electrochromism. Fundamentals and Applications``, von P.M.S. Monk, R.J. Mortimer und D.R. Rosseinsky.
  4. B. Speiser, Angew. Chem., 109, 2635 - 2636 (1997); ,,Grundlagen der Elektrochemie``, von W. Schmickler.
  5. B. Speiser, Angew. Chem., 111, 1396 - 1397 (1999); ,,Leitfaden der Elektrochemie``, von R. Holze.
  6. B. Speiser, Angew. Chem., 114, 1299 - 1300 (2002), ,,Electrochemical Reactions and Mechanisms in Organic Chemistry``, von J. Grimshaw.
  7. B. Speiser, Angew. Chem., 114, 3652 - 3653 (2002), ,,Electrochemistry in Nonaqueous Solvents``, von K. Izutsu.
  8. B. Speiser, Nachr. Chem. Tech. Lab., 51, 53 - 54 (2003), ,,Electrochemical Methods. Guide to Experiments and Applications.``, herausgegeben von F. Scholz.
  9. B. Speiser, Nachr. Chem. Tech. Lab., 51, 54 (2003), ,,Praxis der elektrochemischen Messtechnik. Grundlagen, Schalttechnik, Experimente.``, von H.-J. Haase.
  10. B. Speiser, Anal. Bioanal. Chem., 389, 1657 - 1658 (2007), ,,Encyclopedia of Electrochemistry, Volume 10: Modified Electrodes``, von I. Rubinstein, M. Fujihira und J.F. Rusling (Hrsg.).
  11. B. Speiser, Nachr. Chem. Tech. Lab., 57, 167 - 168 (2009), ,,Spectroelectrochemistry``, von W. Kaim und A. Klein (Hrsg.).

Publikationen in Tagungsbänden ohne ISBN1

  1. B. Speiser, Beiträge zur Klausurtagung der Materialforschungsprojekte MFI 4 und 5 der Universitäten Tübingen und Stuttgart, Tübingen, 1990; Elektroanalytische Simulationen. 12. Theoretische Analyse von katalytischen Elektrodenreaktionen an amperometrischen Biosensoren.
  2. A. Rieker, J. Bracht, P. Hertl und B. Speiser, Abstracts of the 23$^{\rm rd}$ Symposium on Oxidation Processes (Ed.: The Society of Synthetic Organic Chemistry und The Chemical Society of Japan), 1990, S. 227 - 232; Some Aspects of the Anodic Oxidation of Sterically Hindered Anilines and Phenols.
  3. E. Eichhorn, A. Rieker, B. Speiser und H. Stahl, Proc. 67$^{\rm th}$ Annual Meeting of The Chemical Society of Japan, 1994, S. 184 - 185; Schiff-Base Co-Complexes. Electron-Transfer and Ligand-Exchange.

in Chem. Abs. referierte ,,Reports``

  1. B. Speiser und S. Pons, Report TR-8, Order-No. AD-A118708; Chem. Abs. 98, 62065g (1983); Simulation of Edge Effects in Electroanalytical Experiments by Orthogonal Collocation. Part 1. Two-dimensional Collocation and Theory for Chronoamperometry.
  2. B. Speiser und S. Pons, Report TR-9, Order-No. AD-A118709; Chem. Abs. 98, 62063e (1983); Simulation of Edge Effects in Electroanalytical Experiments by Orthogonal Collocation. Part II. The Theory for Cyclic Voltammetry by Collocation.
  3. B. Speiser, A. Rieker und S. Pons, Report, TR-11, Order-No. AD-118711; Chem. Abs. 98, 62062d (1983); Electroanalytical Investigations. - IV. Use of Orthogonal Collocation for the Simulation of Quasireversible Electrode Processes under Potential Scan Conditions.
  4. S. Pons, B. Speiser und J.F. McAleer, Report TR-12, Order-No. AD-A118712; Chem. Abs. 98, 61975s (1983); Orthogonal Collocation Simulation of the Rotating Disk Electrode.
  5. B. Speiser und S. Pons, Report TR-14, Order-No. AD-A118710; Chem. Abs. 98, 62064f (1983); Simulation of Edge Effects in Electroanalytical Experiments by Orthogonal Collocation. Part III. Application to Chronoamperometric Experiments.
  6. J.F. Cassidy, S. Pons, A.S. Hinman und B. Speiser, Report TR-23, Order-No. AD-A136988; Chem. Abs. 101, 13949v (1984); Simulation of Edge Effects in Electroanalytical Experiments by Orthogonal Collocation. Part 4. Application to Voltammetric Experiments.

zur Veröffentlichung angenommene oder im Druck befindliche Publikationen

  1. A. Ruff, Paul Schuler und B. Speiser, J. Solid State Electrochem., im Druck; online-Version: http://dx.doi.org/10.1007/s1008-012-1834-0; Redox-active Silica Nanoparticles. Part 6. Synthesis and Spectroscopic and Electrochemical Characterization of Viologen-Modified Stöber Silica Particles with Diameters of approximately 125 nm.
  2. V. Gierz, A. Seyboldt, C. Maichle-Mössmer, K.W. Törnroos, M.T. Speidel, B. Speiser, K. Eichele und D. Kunz, Organometallics, im Druck; online-Version: http://dx.doi.org/10.1021/om300544g; Dinuclear Coinage-Metal Complexes of Bis(NHC) Ligands: Structural Features and Dynamic Behavior of a Cu−Cu Complex.



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