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Liste der wissenschaftlichen Veröffentlichungen
Professor Dr. Bernd Speiser
- B. Speiser und A. Rieker, J. Chem. Res. (S) 1977,
314 - 315; (M) 1977, 3601 - 3609;
Electrochemical Oxidations. Part 1.
Phenoxy Cations in the Anodic Oxidation of Phenolic Compounds.
- B. Speiser und A. Rieker, Electrochim. Acta 23,
983 - 989 (1978); Elektroanalytische Untersuchungen - I.
Die Auswirkung von Kanteneffekten auf die Zahl der Peaks in
cyclischen Voltammogrammen.
- B. Speiser und A. Rieker, J. Electroanal. Chem. 102,
1 - 20 (1979); Electroanalytical Investigations. Part II.
Application of the Orthogonal Collocation Technique to the Simulation
of Cyclic Voltammograms.
- B. Speiser und A. Rieker, J. Electroanal. Chem. 102,
373 - 395 (1979);
Electrochemical Oxidations. Part IV. Electrochemical
Investigations into the Behaviour of 2,6-Di- tert-butyl-4-(4-dimethylaminophenyl)-phenol. Part 1. Phenol and
the Species Derived from it: Phenoxy Radical, Phenolate Anion and
Phenoxenium Cation.
- B. Speiser, J. Electroanal. Chem. 110, 69 -77 (1980);
Electroanalytical Investigations. Part III. Optimization of
the Dimensionless Parameter
in Orthogonal Collocation
Simulations of Cyclic Voltammograms.
- B. Speiser und A. Rieker, J. Electroanal. Chem. 110,
231 - 246 (1980); Electrochemical Oxidations. Part V. Electrochemical
Investigations into the Behaviour of 2,6-Di- tert-butyl-4-(4-dimethylaminophenyl)-phenol. Part 2. Anodic
Oxidation in the
Presence of 2,6-Dimethylpyridine and the Mechanism of the Formation
of the Phenoxenium Cation.
- B. Speiser, Chemie in uns. Zeit 15, 21 - 26 (1981);
Elektroanalytische Methoden. I. Grundlagen und Chronoamperometrie.
- B. Speiser, Chemie in uns. Zeit 15, 62 - 67 (1981);
Elektroanalytische Methoden. II. Cyclische Voltammetrie.
- B. Speiser und S. Pons, Can. J. Chem. 60, 1352 - 1362
(1982);
Simulation of Edge Effects in Electroanalytical Experiments
by Orthogonal Collocation. Part 1. Two-dimensional Collocation
and Theory for Chronoamperometry.
- B. Speiser und S. Pons, Can. J. Chem. 60, 2463 - 2476
(1982);
Simulation of Edge Effects in Electroanalytical Experiments by
Orthogonal Collocation. Part 2. Theory for Cyclic Voltammetry.
- B. Speiser, A. Rieker und S. Pons, Electrochim. Acta
27, 1171 - 1176 (1982);
Electroanalytical Investigations. - IV.
Use of Orthogonal Collocation for the Simulation of Quasireversible
Electrode Processes under Potential Scan Conditions.
- S. Pons, B. Speiser und J.F. McAleer, Electrochim. Acta
27, 1177 - 1179 (1982);
Orthogonal Collocation Simulation of the Rotating Disk Electrode.
- S. Pons, B. Speiser, J.F. McAleer und P.P. Schmidt,
Electrochim. Acta 27, 1711 -1714 (1982);
Simulation of the Dropping Mercury Electrode by Orthogonal
Collocation.
- B. Speiser und S. Pons, Can. J. Chem. 61, 156 -162
(1983);
Simulation of Edge Effects in Electroanalytical Experiments
by Orthogonal Collocation. Part 3. Application to Chronoamperometric
Experiments.
- B. Speiser, A. Rieker und S. Pons, J. Electroanal. Chem. 147, 205 - 222 (1983); Electrochemistry of Anilines. Part I.
Oxidation of 2,6-Di-tert-butyl-anilines to Radical Cations:
General Considerations, Electroanalytical Experiments and
Spectroscopy.
- B. Speiser, A. Rieker und S. Pons, J. Electroanal. Chem. 159, 63 - 88 (1983); Electrochemistry of Anilines. Part II.
Oxidation to Dications, Electrochemical and UV/VIS
Spectroelectrochemical Investigation.
- J.F. Cassidy, S. Pons, A.S. Hinman und B. Speiser, Can. J. Chem. 62, 716 - 720 (1984); Simulation of Edge Effects in
Electroanalytical Experiments by Orthogonal Collocation. Part 4.
Application to Voltammetric Experiments.
- B. Speiser, J. Electroanal. Chem. 171, 95 - 109 (1984);
Electroanalytical Investigations. Part V. The Simulation of Fast
Chemical Reactions in Cyclic Voltammetry by a Combination of
the Orthogonal Collocation Method and the Heterogeneous
Equivalent Approach.
- B. Speiser, Anal. Chem. 57, 1390 - 1397 (1985);
Multiparameter Estimation: Extraction of Information from Cyclic
Voltammograms.
- P. Hertl, A. Rieker und B. Speiser, J. Electroanal. Chem.
200, 147 - 158 (1986); Electrochemistry of Anilines. Part III.
Electrochemical Oxidation of Sterically Hindered 4-Aminobiphenyls
and Correlation of Formal Potentials with Hammett
Values.
- P. Hertl und B. Speiser, J. Electroanal. Chem. 217,
225 - 238 (1987); Electroanalytical Investigations. Part VI. The
Simulation of Fast Chemical Equilibrium Reactions in Cyclic
Voltammetric Reaction-Diffusion Models with Spline Collocation.
- P. Hertl und B. Speiser, J. Electroanal. Chem. 235,
57 - 70 (1987);
Electroanalytical Investigations. Part VII. The Simulation
of Fast Chemical Equilibrium Reactions in Cyclic Voltammetric
Reaction-Diffusion Models with a Combination of the
Heterogeneous Equivalent Technique and Orthogonal Collocation.
- P. Urban und B. Speiser, J. Electroanal. Chem. 241, 17 - 31 (1988);
Electroanalytical Investigations. Part VIII. The Use of an
Expanding Simulation Space in the Simulation of Electrochemical
Reaction-Diffusion Models with Orthogonal Collocation.
- P. Hertl und B. Speiser, J. Electroanal. Chem. 250,
237 - 256 (1988);
Electroanalytical Simulations. Part IX - The Simulation of a
Second-Order Chemical Reaction Preceding a Reversible Electron
Transfer under Cyclic Voltammetric Conditions Using Orthogonal
Collocation.
- B. Scharbert und B. Speiser, J. Chemomet. 3, 61 - 80
(1988);
Chemical Information from Electroanalytical Data. Part 1.
Determination of System Parameters for Quasi-Reversible Electron
Transfer Reactions from Cyclic Voltammetric Test Data and Data
for the Reduction of Cerium(IV)bis(octaethylporphyrinate).
- A. Dettling, A. Rieker und B. Speiser, Tetrahedron Lett.
29, 4533 - 4534 (1988); Reversible Electrochemical Oxidation of
2,5,8,11-Tetra-tert-butyl-peri-xanthenoxanthene to its
Radical Cation and Dication.
- B. Speiser in G. Gauglitz (Hrsg.), Softwareentwicklung in der
Chemie, Band 3, Springer, Berlin, 1989, S. 321 - 332;
EASIEST - A Program System for Electroanalytical Simulation and
Parameter Estimation. Part 2.
EASIEST - ein Programmsystem zur Simulation von und
Parameterbestimmung aus elektroanalytischen Experimenten.
- B. Speiser und A. Rieker, Nachr. Chem. Tech. Lab. 37,
616 - 618 (1989); Energie durch elektrochemisch induzierte Kernfusion?
- B. Speiser, Comput. Chem., 14, 127 - 140 (1990);
EASIEST - A Program System for Electroanalytical Simulation and
Parameter Estimation. Part 1. Simulation of Cyclic Voltammetric and
Chronoamperometric Experiments.
- B. Speiser in J. Gasteiger (Hrsg.), Software Development
in Chemistry 4, Springer, Berlin, 1990, S. 321 - 330;
Electroanalytical Simulations. Part 10. The Simulation of Fast
Second Order Reactions in Electrochemical Systems.
- A. Rieker und B. Speiser, Tetrahedron Lett. 31,
5013 - 5014 (1990);
Electrochemistry of Anilines. Part 5.
Spectroscopic and Electrochemical Characterization of a Persistent
Biphenylyl Nitrenium Ion.
- B. Speiser, Trends in Anal. Chem., 10, 9 - 11 (1991);
EASIEST - A Program System for Electroanalytical Simulation and
Parameter Estimation. Part 3.
Second-order Catalytic Electrode Reactions at Amperometric
Biosensors. The Application of Polynomial and B-Spline Interpolation
to the Description of Cyclic Voltammetric Features.
- B. Speiser, Anal. Chim. Acta, 243, 301 - 310 (1991);
Electroanalytical Simulations. Part 11. Orthogonal
Collocation Simulation of Fast Second-order Chemical Reactions
Coupled to an Electron Transfer with a Heterogeneous Equivalent
Formulation.
- B. Speiser, J. Electroanal. Chem., 301, 15 - 35 (1991);
Chemical Information from Electroanalytical Data. Part 2.
Determination of Rate and Equilibrium Constants of a Chemical Reaction
Preceding a Reversible Electron Transfer from Cyclic Voltammetric
Data; Erratum: J. Electroanal. Chem. 306, 313 (1991).
- P. Hertl, A. Rieker und B. Speiser, J. Electroanal. Chem., 301, 37 - 52 (1991); Electrochemistry of
Anilines. Part 4. Determination of Rate and Equilibrium Constants
for the Protonation of 2,6-Di-tert-butyl-4-(4
-R-phenyl)-anilines in Acetonitrile from
Cyclic Voltammetric Data.
Erratum: J. Electroanal. Chem. 306, 313 (1991).
- B. Speiser, A. Leverenz und M. Hanack, Synth. Met., 41 - 43, 2979 - 2982 (1991);
The Mechanism of Na[PcCo(CN)
] Electrocrystallization
-- Analysis of Adsorption Phenomena by a Comparison of Simulated and
Experimental Cyclic Voltammograms.
- A. Nishinaga, K. Tajima, B. Speiser, E. Eichhorn, A. Rieker, H. Ohya-Nishiguchi und K. Ishizu, Chem. Lett. 1991,
1403 - 1406; Substituent Effects on the Formal Potential of the
Co(II)/Co(III) Redox Couple for Co(salen) Derivatives.
- B. Speiser and A. Rieker, J. Org. Chem., 56,
4664 - 4671 (1991);
Electrochemistry of Anilines. Part 6. Reactions of Electrogenerated
Biphenylyl Nitrenium Ions.
- A. Rieker, B. Speiser, K.-M. Mangold und M. Hanack, Z.
Naturforsch., 46b, 1125 - 1126 (1991);
Potential Error Sources in Combined Electrochemistry/Neutron Detection
Experiments.
- U. Löffler, B. Speiser und W. Göpel, Electroanalysis, 3, 917 - 923 (1991);
The Determination of Electron Transfer Parameters for
Monosubstituted Ferrocenes Suitable as Mediators in Amperometric
Biosensors.
- A. Leverenz und B. Speiser, J. Electroanal. Chem.,
318, 69 - 89 (1991);
Electroanalytical Simulations.
Part 13. The Simulation of Adsorption Processes at an Electrode by
Orthogonal Collocation Algorithms.
- E. Eichhorn, A. Rieker und B. Speiser, Anal. Chim. Acta, 256, 243 - 249 (1992);
Numerical Method to Correct
Drop Errors in Cyclic Voltammetric
Potential Data for (Quasi)Reversible Electrode Processes.
- B. Gollas und B. Speiser, Angew. Chem., 104, 336 - 338
(1992); Angew. Chem. Int. Ed. Engl., 31, 332 - 334 (1992);
Elektrochemie von Triazenen. Teil 1. Elektrochemische Oxidation von
1-p-Dimethylaminophenyl-3,3-dimethyltriazen --
Cyclovoltammetrischer Nachweis eines Triazen-Radikalkations und
-Dikations.
- A. Rieker, P. Hertl und B. Speiser, in R. Louw und P. Mulder
(Hrsg.), Proc. Sixth Int. Symp. Org. Free Rad., Noordwijkerhout,
Niederlande,
1992, S. 256 - 259 (ISBN: 90-9004445-0);
Persistent Radicals Derived from Primary Anilines.
- A. Leverenz, B. Speiser und M. Hanack, J. Electroanal. Chem., 323, 275 - 287 (1992); Cyclic Voltammetry of
Na[PcCo(CN)
] -- Analysis of
Adsorption Phenomena During Electrooxidation.
- A. Rieker, B. Speiser und H. Straub,
DECHEMA-Monographien, Band 125, 777 - 782 (1992);
Reaktionen anodisch erzeugter Phenoxeniumionen mit Nucleophilen.
- A. Nishinaga, S. Förster, A. Rieker, E. Eichhorn und
B. Speiser, Tetrahedron Lett. 33, 4425 - 4428 (1992);
Co(salen) Catalyzed Oxidation of 2,4,6-Trisubstituted
Anilines with t-butyl Hydroperoxide.
- B. Speiser und H. Stahl, Tetrahedron Lett. 33,
4429 - 4432 (1992);
Electrochemistry of Triazenes. Part 2.
Formation of the 2,7-Dimethoxy-5,10-dimethyl-5,10-dihydrophenazine
Radical Cation during Oxidation of 1,3-Diaryl-3-methyltriazenes.
- E. Eichhorn, A. Rieker und B. Speiser, Angew. Chem., 104, 1246 - 1248 (1992); Angew. Chem. Int. Ed., 31,
1215 - 1217 (1992);
Elektrochemie von Oxygenierungskatalysatoren. Teil 1. Die
elektrochemische Oxidation von N,N
-Bis(salicyliden)ethylendiiminato-kobalt(II)
in Lösungsmittelgemischen -- Ein Beispiel für ein
Leiterschema mit gekoppelten Elektronentransfer- und
Lösungsmittelaustauschreaktionen.
- E. Eichhorn, A. Rieker, B. Speiser, J. Sieglen
und J. Strähle, Z. Naturforsch., 48b, 418 - 424 (1993);
Electrochemistry of Oxygenation Catalysts. Part 2.
Improved Synthesis, Crystal Structure, and Electrochemical Properties of
N,N
-Bis(salicyliden)-ethylenediaminato
Cobalt(III) Chloride.
- C. Schulz und B. Speiser,
J. Electroanal. Chem., 354, 255 - 271 (1993);
Electroanalytical Simulations.
Part 14. Simulation of Frumkin-Type Adsorption Processes by
Orthogonal Collocation under Cyclic Voltammetric Conditions.
- B. Speiser,
Acta Chem. Scand., 47, 1238 -1240 (1993);
Electrochemical Simulations. Part 15. Advanced
Orthogonal Collocation Techniques in Problem Situations of the
EC
Mechanism. A Comment on the Paper ,,Efficiency of
Electrochemical Kinetic Simulations by Orthogonal Collocation and
Finite Difference Methods. A Comparison`` by L.K. Bieniasz and D.
Britz.
- T. Vering, W. Schuhmann, D. Seiwald, H.-L. Schmidt,
B. Speiser und L. Ye,
J. Electroanal. Chem., 364, 277 - 279 (1994);
A New Multipuls-Method for Potentiometric Measurements of Enzymatic
Redox Reactions.
- E. Eichhorn und B. Speiser,
J. Electroanal. Chem., 365, 207 - 212 (1994);
Electrochemistry of Oxygenation
Catalysts. Part 4. Solvent Composition Dependent Isopotential
Points in Cyclic Voltammograms of Co(salen)
.
- B. Gollas, B. Krauß, B. Speiser und H. Stahl,
Curr. Sep., 13, 42 - 44 (1994);
Design of a
Single-Unit Haber-Luggin Capillary/Dual Reference-Electrode System.
- L. Dunsch, B. Gollas, A. Neudeck, A. Petr, B. Speiser und H.
Stahl,
Chem. Ber., 127, 2423 - 2429 (1994);
Electrochemistry of Triazenes. Part 3. One-Electron Oxidation
of Aryltriazenes to Radical Cations.
- E. Eichhorn, A. Rieker, B. Speiser und H. Stahl,
in S. Torii (Hrsg.),
Novel Trends in Electroorganic Synthesis, Proc. 2
Intl. Symp.
on Electroorg. Synth., Kodansha, Tokyo, 1994 (Publ. 1995),
S. 173 - 174 (ISBN: 4-06-207503-2);
Electrochemical Investigation of Oxygenation Catalysts.
- B. Speiser und H. Stahl,
Angew. Chem., 107, 1222 - 1224 (1995);
Angew. Chem. Int. Ed., 34, 1086 - 1089 (1995);
Elektrochemie von
Oxygenierungskatalysatoren. 5. Mitteilung. Komplexierung von
[N,N
-Bis(salicyliden)ethylendiiminato]cobalt(III) durch Aniline in Dimethylformamid.
- X. Wei und B. Speiser,
Electrochim. Acta, 40, 2477 - 2482 (1995);
Electrochemistry of Triazenes. Part 4.
Reaction of Diazonium Ions Generated Electrochemically from
1-Aryl-3,3-dimethyltriazenes in Acetonitrile.
- B. Gollas, B. Speiser, J. Sieglen und J. Strähle,
Organometallics, 15, 260 - 271 (1996);
Electrochemistry of Ruthenium Metallocenes. 1.
Synthesis, NMR, and Anodic Electrochemical Behavior of
Vinyl-Substituted Ruthenium Cyclophane Complexes.
- G. Frenking, A. Rieker, J. Salbeck und B. Speiser,
Z. Naturforsch., 51b, 377 - 380 (1996);
2,5,8,11-Tetra-tert-butyl-peri-xanthenoxanthene and
its Dication -- Spectroelectrochemistry and Model Calculations
on a Dioxa-22-
-system.
- B. Gollas, B. Speiser, H. Stahl, J. Sieglen und J. Strähle,
Z. Naturforsch., 51b, 388 - 398 (1996);
Electrochemistry of
Oxygenation Catalysts. Part 6. Electrosynthesis, Structure,
Analytical, and Electrochemical Properties of Monomeric [Co
(salen)(DMF)
]
X
Salts (X = PF
, ClO
).
- X. Wei und B. Speiser,
Electrochim. Acta, 42, 73 - 79 (1997);
Ring Formation from 2-Arylazo-3-aminocrotononitriles to
1,2,3[2H]-triazole-4-carbonitriles and Pyrazoles
by Anodic Oxidation.
- B. Speiser, J. Electroanal. Chem., 413, 67 - 79 (1996);
Electroanalytical Simulations. Part 16. Simulation of
Controlled Current Bulk Electrolysis Experiments by Orthogonal
Collocation: General Model and Simple Charge Transfer Mechanisms.
- B. Speiser,
Angew. Chem., 108, 2623 - 2626 (1996);
Angew. Chem. Intl. Ed. Engl. 35, 2471 - 2474 (1996);
Elektronentransfer und chemische Reaktion: schrittweise
oder konzertiert? -- Zur Konkurrenz von nucleophiler Substitution und
Elektronenübertragung.
- M. Hecht, F.A. Schultz und B. Speiser,
Inorg. Chem., 35, 5555 - 5563 (1996);
Ligand Structural Effects on the Electrochemistry of
Chromium(III) Aminocarboxylate Complexes.
- B. Gollas und B. Speiser,
in F. Beck (Hrsg.),
Elektrochemie der Elektronenleiter. Metalle - Oxide - Polymere,
Beiträge der Jahrestagung der
GDCh-Fachgruppe Angewandte Elektrochemie, GDCh-Monographie, Band
3, Gesellschaft Deutscher Chemiker, Frankfurt, 1996, S. 580
(ISBN: 3-924763-56-9);
Elektrochemische Redoxreaktionen von Rutheniumkomplexen
aromatischer Liganden: Redoxpolymerfilme aus
Vinylcyclophan-Ruthenium-Metallocenen.
- S. Dümmling, E. Eichhorn, S. Schneider, B. Speiser und M. Würde,
Curr. Sep., 15, 53 - 56 (1996);
Recycling of the Supporting Electrolyte Tetra(n-butyl)ammonium
Hexafluorophosphate from Used Electrolyte Solutions.
- E. Eichhorn, A. Rieker und B. Speiser,
Z. anorg. allg. Chem., 623, 810 - 817 (1997);
Elektrochemie von Oxygenierungskatalysatoren. Teil 7.
Synthese und Elektrochemie von Komplexen des Co(salen)-Typs mit
zwei potentiellen über Spacer angebundenen axialen basischen Liganden.
- B. Gollas, B. Speiser, J. Sieglen, J. Strähle und C.
Maichle-Mössmer,
Z. Krist., 212, 269 - 270 (1997);
Crystal Structure of Bis(biphenyl)chromium(I)iodide
Chloroform Solvate, [(C
H
)
CrI]
CHCl
.
- B. Gollas, B. Speiser, J. Sieglen, J. Strähle und
C. Maichle-Mössmer,
Z. Krist., 212, 271 - 272 (1997);
Crystal Structure of
E-4-(2
-Ethoxycarbonyl-2
-methyl)-ethenyl-[2
]paracyclophane,
C
H
O
.
-
E. Eichhorn, A. Rieker, B. Speiser und H. Stahl,
Inorg. Chem., 36, 3307 - 3317 (1997);
Electrochemistry of Oxygenation Catalysts. Part 3.
Thermodynamic Characterization of
Electron Transfer and Solvent Exchange Reactions of
Co(salen)/[Co(salen)]
in DMF, Pyridine and Their Mixtures.
- B. Gollas, I. Hesse, R. Lotz, H. Pasch, B. Speiser und I. Zagos,
Liebigs. Ann./Recueil, 1997, 2255 - 2264;
Electrochemical Oxidation of 4-Ethenyl-[
]paracyclophane:
Cyclic Voltammetry, Electrosynthesis of Polymers, Analysis by
Liquid Chromatography and Mass Spectrometry.
- N. Kuhn, G. Weyers, S. Dümmling, und B. Speiser,
Phosphorus, Sulfur, and Silicon 128, 45 - 62 (1997);
Derivate des Imidazols. 25.
Reduktion von Carben-Addukten des Kohlenstoffdisulfids:
ein neuer Weg zu elektronenreichen 1,1-Dithiolaten.
- B. Speiser, M. Würde und C. Maichle-Mössmer,
Chem. Eur. J., 4, 222 - 233 (1998);
Electrochemistry of Polyaminobenzenes, Part 1.
Electrochemical Oxidation of Hexakis(dimethylamino)benzene.
- L.K. Bieniasz und B. Speiser,
J. Electroanal. Chem., 441, 271 - 285 (1998);
Use of Sensitivity Analysis Methods in the
Modelling of Electrochemical Transients. Part 1. Gaining More Insight
into the Behaviour of Kinetic Models.
Erratum: J. Electroanal. Chem., 452, 139 (1998);
- L.K. Bieniasz, S. Dümmling, B. Speiser und M. Würde,
J. Electroanal. Chem., 447, 173 - 186 (1998);
Use of Sensitivity Analysis Methods in the Modelling of Electrochemical
Transients. Part 2. Model Expansion and Model Reduction.
- L.K. Bieniasz und B. Speiser,
J. Electroanal. Chem., 458, 209 - 229 (1998);
Use of Sensitivity Analysis Methods in the Modelling of Electrochemical
Transients. Part 3. Statistical Error/Uncertainty Propagation in
Simulation and in Nonlinear Least-Squares Parameter Estimation.
- E. Lindner, I. Krebs, R. Fawzi, M. Steimann und B. Speiser,
Organometallics, 18, 480 - 489 (1999);
Preparation, Properties, and Reactions of Metal-Containing Heterocycles.
Part 98. Synthesis, Structure, and Electrochemistry of
Osmametallocenophanes with Different Ring Size.
- B. Speiser, Curr. Org. Chem., 3, 171 - 191 (1999);
From Cyclic Voltammetry to Scanning Electrochemical Microscopy:
Modern Electroanalytical Methods to Study Organic Compounds, Materials,
and Reactions.
- B. Speiser und S. Dümmling, in J. Russow, G. Sandstede und R. Staab
(Hrsg.), GDCH-Monographien, Band 14, 33 - 39 (1999);
Zweielektronentransfer-Redoxsysteme.
Teil 1. Cyclovoltammetrische Charakterisierung von
Zweielektronentransfers an organischen und metallorganischen
Molekülen. (gleichzeitig: Electrochemie von Rutheniummetallocenen,
Teil 2)
- B. Speiser, C. Tittel, W. Einholz und R. Schäfer,
J. Chem. Soc., Dalton Trans., 1999, 1741 - 1751;
Two-Electron-Transfer Redox Systems. Part 2.
Redox Reactions of the Boron Subhalide Clusters
B
Cl
(
) Investigated by Electrochemical
and Spectroscopic Methods.
- S. Dümmling, B. Speiser, N. Kuhn und G. Weyers,
Acta Chem. Scand., 53, 876 - 886 (1999);
Two-Electron-Transfer Redox Systems. Part 3.
Electrochemical Reduction of
N,N
-Dialkyl-4,5-dimethylimidazolium-2-dithiocarboxylates
to 1,1-Dithiolate Anions in THF. Steric Modulation of Potential
Ordering by Substituents.
- M.P. Feth, U. Reinöhl, T.S. Ertl, M. Seiler, H. Bertagnolli,
S. Maier, B. Speiser und H.A. Mayer,
HASYLAB Ann. Rep. 780 - 781 (1999);
EXAFS Investigation of Organometallic Iridium Complexes.
- B. Speiser, M. Würde und M.G. Quintanilla, Electrochem. Commun.,
2, 65 - 68 (2000);
Electrochemistry of Polyaminobenzenes. Part 2. Oxidation of
Hexakis(dimethylamino)benzene at High Potentials.
- N. Kuhn, H. Kotowski, M. Steimann, B. Speiser, M. Würde und G. Henkel,
J. Chem. Soc., Perkin Trans. 2,
2000, 353 - 363;
Synthesis, Oxidation and Protonation of
Octamethyl-1,1
-bipyrrole.
- B. Gollas, B. Speiser, I. Zagos und C. Maichle-Mössmer,
J. Organomet. Chem., 602, 75 - 90 (2000);
Electrochemistry of Ruthenium Metallocenes. Part 3.
Synthesis, Spectroscopic Characterization, and Electrochemical
Redox Reactions of Ruthenium Arene Complexes with Methacrylic Acid and
Methacrylate Ester Substituted Cyclophane Ligands.
- J.J. Wolff, A. Zietsch, B. Nuber, F. Gredel, B. Speiser und M. Würde,
J. Org. Chem., 66, 2769 - 2777 (2001);
Electrochemistry of Polyaminobenzenes. Part 3.
Hexaaminobenzene Derivatives: Synthesis and Unusual Oxidation Behavior.
- S. Buchmann, H.A. Mayer, B. Speiser, M. Seiler,
H. Bertagnolli, S. Steinbrecher und E. Plies,
Electrochim. Acta, 46, 3207 - 3217 (2001);
Electrochemistry of Transition Metal Complex Catalysts. Part 8.
One-Electron Oxidation of an Iridium Complex with a Cyclohexane-Derived
Tripod Phosphine Ligand -- Cyclic Voltammetry and Preparative
Electrolysis.
- B. Speiser, K. Ludwig, A. Stauß und M.G. Quintanilla,
Proc. Electrochem. Soc., 2001-14, 69 - 72 (2001);
Two-Electron-Transfer Redox Systems. Part 4.
Electrochemical Oxidation of Hexa(benzylthio)benzene -- Formation and
Reaction of a Radical Cation.
- B. Speiser, W. Märkle und S. Heiß, in J. Russow und H.J. Schäfer,
GDCH-Monographie, Band 23,
Elektronenübertragung in Chemie und Biochemie, S. 285 - 292 (2001);
Anodische Oxidation von Benzaldehydphenylhydrazonen in Gegenwart von
Nitrilen
- W. Einholz, K. Vaas, C. Wieloch, B. Speiser, T. Wizemann, M. Ströbele
und H.-J. Meyer, Z. anorg. allgem. Chem., 628, 258 - 268 (2002);
Zweielektronentransfer-Redoxsysteme, Teil 5.
Chemische und cyclovoltammetrische Untersuchung der Redoxreaktionen der
Decahalogendecaborate closo-[B
X
und hypercloso-[B
X
(X = Cl, Br).
Kristallstrukturanalyse von
Cs
[B
Br
]
2 H
O.
- B. Speiser,
Anal. Bioanal. Chem., 372, 29 - 30 (2002);
Molecular Electrochemistry.
- K. Ludwig und B. Speiser,
J. Electroanal. Chem. 531, 1 - 8 (2002);
Electroanalytical Simulations, Part 17.
Calculation of Open Circuit Potentials during Fractional Electrolysis
in Two-Electron-Transfer Systems.
- K. Ludwig, M.G. Quintanilla, B. Speiser und A. Stauß,
J. Electroanal. Chem. 531, 9 - 18 (2002);
Two-Electron-Transfer Redox Systems. Part 6.
Two-Electron Oxidation of Hexakis(benzylthio)benzene
-- A Study by Electrolysis and Cyclic Voltammetry.
- H.A.Y. Mohammad, J.C. Grimm, K. Eichele, H.-G. Mack, B. Speiser,
F. Novak, M.G. Quintanilla, W.C. Kaska und H.A. Mayer,
Organometallics 21, 5775 - 5784 (2002);
C-H Oxidative Addition with a (PCP)Ir
-Pincer-Complex.
- B. Speiser, T. Wizemann und M. Würde,
Inorg. Chem., 42, 4018 - 4028 (2003);
Two-Electron-Transfer Redox Systems. Part 7. Two-Step Electrochemical
Oxidation of the Boron Subhalide Cluster Dianions B
X
(X = Cl, Br, I)
- S. Buchmann, H.A. Mayer, B. Speiser, M. Seiler, M.P. Feth,
H. Bertagnolli, S. Steinbrecher und E. Plies,
Electrochim. Acta, 48, 2725 - 2737 (2003);
Electrochemistry of Transition Metal Complex Catalysts. Part 9.
One- and Two-Electron Oxidation of Iridium Complexes with
Cyclohexane-Derived Tripod Phosphine Ligands; Erratum:
Electrochim. Acta, 48, 4319 - 4320 (2003).
-
F. Novak, B. Speiser, E. Lindner, Z.-L. Lu und H.A. Mayer,
Angew. Chem., 116, 2059 - 2062 (2004);
Elektrochemie von Übergangsmetallkatalysatoren. Teil 11.
Eine chemisch modifizierte Platinelektrode als zweizähniger
Diaminligand zur Bildung wohldefinierter immobilisierter
Bis(
-P-ether-phosphan)(diamin)ruthenium(II)-Komplexe;
Angew. Chem. Int. Ed. 43, 2025 - 2028 (2004);
Electrochemistry of Transition Metal Complex Catalysts. Part 11.
A Chemically Modified Platinum Electrode as a Bidentate Diamine
Ligand for Forming Well-Defined, Immobilized
Bis(
-P-ether-phosphane)(diamine)ruthenium(II)
Complexes; Berichtigung: Angew. Chem., 116, 2934 (2004).
- B. Schetter und B. Speiser,
J. Organomet. Chem., 689, 1472 - 1480 (2004);
Reaction of Ferrocenecarboxylic Acid With
N,N
-Disubstituted
Carbodiimides. Synthesis, Spectroscopic and X-ray Crystallographic
Analysis of N,N
-Disubstituted
N-Ferrocenoylureas
and Identification of a One-Pot Coupling Reagent for
the Formation of Ferrocenecarboxamides in a Non-Aqueous Solvent;
Erratum: J. Organomet. Chem., 689, 2743 (2004);
- K. Ludwig, L. Rajendran und B. Speiser,
J. Electroanal. Chem., 568, 203 - 214 (2004);
EChem++ - An Object Oriented Problem Solving Environment for
Electrochemistry. Part 1. A C++ Class Collection for
Electrochemical Excitation Functions; Erratum:
J. Electroanal. Chem., 571, 119 (2004).
- F. Novak, B. Speiser, H.A.Y. Mohammad und H.A. Mayer,
Electrochim. Acta, 49, 3841 - 3853 (2004);
Electrochemistry of Transition Metal Complex Catalysts. Part 10.
Intra- and Intermolecular Electrochemically Activated
C-H Addition to the Central Metal Atom of a P-C-P-Pincer
Iridium Complex.
- K. Ludwig und B. Speiser,
J. Chem. Inf. Comput. Sci., 44, 2051 - 2060 (2004);
EChem++ - An Object-Oriented Problem Solving Environment for
Electrochemistry. 2. The Kinetic Facilities of Ecco - A
Compiler for (Electro-)Chemistry; Erratum: J. Chem. Inf.
Comput. Sci., 46, 2762 (2006).
- W. Märkle, B. Speiser, C. Tittel und M. Vollmer,
Electrochim. Acta, 50, 2753 - 2762 (2005);
Combinatorial Micro Electrochemistry. Part 1. Automated
Micro Electrosynthesis of Iminoquinol Ether and
[1,2,4]Triazolo[4,3-a]pyridinium Perchlorate Collections in
the Wells of Microtiter Plates.
- T. Erichsen, S. Reiter, W. Märkle, C. Tittel, V. Ryabova,
E.M. Bonsen, G. Jung, B. Speiser und W. Schuhmann,
Rev. Sci. Instrum., 76, 062204-1 - 062204-11 (2005);
Combinatorial Micro Electrochemistry. Part 2. Development and
Evaluation of an Electrochemical Robotic System.
- W. Märkle und B. Speiser,
Electrochim. Acta, 50, 4916 - 4925 (2005);
Combinatorial Microelectrochemistry. Part 3. On-line Monitoring of
Electrolyses by Steady-State Cyclic Voltammetry at Microelectrodes.
- E. Lindner, Z.-L. Lu, H.A. Mayer, B. Speiser, C. Tittel und I. Warad,
Electrochem. Commun., 7, 1013 - 1020 (2005);
Combinatorial Micro Electrochemistry. Part 4. Cyclic Voltammetric
Redox Screening of Homogeneous Ruthenium(II) Hydrogenation Catalysts
(also: Electrochemistry of Transition Metal Complexes, Part 12).
- E.P. Sapozhnikova, M. Bogdan, B. Speiser, und W. Rosenstiel,
J. Electroanal. Chem., 588, 15 - 26 (2006);
EChem++ - An Object-Oriented Problem Solving Environment for
Electrochemistry. Part 3. Classification of Voltammetric Signals by the
Fuzzy ARTMAP Neural Network with Respect to Reaction Mechanisms.
- K. Ludwig und B. Speiser,
J. Electroanal. Chem., 588, 74 - 87 (2006);
EChem++ - An Object Oriented Problem Solving Environment for
Electrochemistry: Part 4. Adaptive Multilevel Finite Elements Applied to
Electrochemical Models. Algorithm and Benchmark Calculations.
- S. Eisele, M. Schwarz, B. Speiser und C. Tittel,
Electrochim. Acta, 51, 5304 - 5306 (2006);
Diffusion Coefficient of Ferrocene in
1-Butyl-3-methylimidazolium Tetrafluoroborate -- Concentration
Dependence and Solvent Purity.
- A. Budny, F. Novak, N. Plumeré, B. Schetter, B. Speiser, D. Straub,
H.A. Mayer und M. Reginek,
Langmuir, 22, 10605 - 10611 (2006);
Redox-Active Silica Nanoparticles. Part 1.
Electrochemistry and Catalytic Activity of
Spherical, Nonporous Silica Particles with Nanometric Diameters and
Covalently Bound Redox-active Modifications
(auch: Electrochemistry of Transition Metal Complexes, Part 13).
- K. Ludwig und B. Speiser,
J. Electroanal. Chem., 608, 91 - 101 (2007);
EChem++ - An Object Oriented Problem Solving Environment for
Electrochemistry. Part 5.
A Differential-Algebraic Approach to the Error Control of
Adaptive Algorithms.
- K. Ludwig, I. Morales und B. Speiser,
J. Electroanal. Chem., 608, 102 - 110 (2007);
EChem++ - An Object Oriented Problem Solving Environment for
Electrochemistry. Part 6.
Adaptive Finite Element Simulations of Controlled-Current
Electrochemical Experiments
- N. Plumeré und B. Speiser,
Electrochim. Acta, 53, 1244 - 1251 (2007);
Redox-Active Silica Nanoparticles. Part 2.
Photochemical Hydrosilylation
on a Hydride Modified Silica Particle Surface for the Covalent
Immobilization of Ferrocene.
- N. Plumeré, B. Speiser, H. A. Mayer, D. Joosten, and L. Wesemann,
Chem. Eur. J., 15, 936 - 946 (2009).
Redox-Active Silica Nanoparticles, Part 3.
High-Temperature Chlorination-Reduction Sequence for the Preparation of
Silicon Hydride Modified Silica Surfaces.
- M. Schwarz und B. Speiser,
Electrochim. Acta, 54, 3735 - 3744 (2009);
Combinatorial Micro-Electrochemistry. Part 5.
Electrosynthesis Screening of the Electroreductive Coupling
of
,
-Unsaturated Esters and
Allyl Bromides in a Room Temperature Ionic Liquid.
- N. Plumeré, B. Speiser, B. Dietrich, K. Albert, J.J. Pesek und M.T. Matyska,
Langmuir, 25, 13481 - 13487 (2009);
Thermally Induced Radical Hydrosilylation for Synthesis
of C18 HPLC Phases from Highly Condensed Si-H Terminated Silica Surfaces.
- F. Novak, N. Plumeré, B. Schetter, B. Speiser, D. Straub,
H.A. Mayer, M. Reginek, K. Albert, G. Fischer, C. Meyer, H.-J. Egelhaaf
and B. Børresen,
J. Solid State Electrochem., 14, 289 - 303 (2010);
Redox-active Silica Nanoparticles. Part 4.
Synthesis, Size Distribution, and
Electrochemical Adsorption Behavior of Ferrocene- and
(Diamine)(diphosphine)-ruthenium(II)-modified Stöber Silica
Colloidal Particles.
- J. Janisch, A. Ruff, B. Speiser, C. Wolff, J. Zigelli, S. Benthin,
V. Feldmann und H.A. Mayer,
J. Solid State Electrochem., 15, 2083 - 2094 (2011);
on-line-Version: DOI 10.1007/s10008-011-1399-3;
Consistent Diffusion Coefficients of Ferrocene in some Non-Aqueous
Solvents: Electrochemical Simultaneous Determination together with
Electrode Sizes and Comparison to Pulse Gradient Spin Echo NMR Results.
- N. Plumeré, A. Ruff, B. Speiser, V. Feldmann und H.A. Mayer,
J. Colloid Interface Sci., 368, 208 - 219 (2012);
on-line-Version: DOI 10.1016/j.jcis.2011.10.070;
Redox-active Silica Nanoparticles. Part 5.
Stöber Silica Particles as Basis for Redox-active Modifications
-- Particle Shape, Size, Polydispersity and Porosity.
- J. Schäfer, M. Scheurer, B. Speiser, W. Kuznik und I.V. Kityk,
Spectrochim. Acta A, 95, 193 - 98 (2012);
on-line-Version: http://dx.doi.org/10.1016/j.saa.2012.04.039;
Electrochemistry and DFT Simulation of Optical Spectra for
N-Ferrocenoyl-N
-
-decenoyl-ethylenediamine.
- S. Benthin und B. Speiser,
J. Electroanal. Chem., 682, 147 - 157 (2012);
online-Version: http://dx.doi.org/10.1016/j.jelechem.2012.07.024;
EChem++ - An Object Oriented Problem Solving Environment for
Electrochemistry. Part 7. Simulation of Equilibrium Electron Transfer
Processes with Implicit Dirichlet Boundary Conditions.
- S. Biswas, M. Müller, C. Tönshoff, K. Eichele, C. Maichle-Mössmer,
A. Ruff, B. Speiser und H.F. Bettinger,
Eur. J. Org. Chem., 4634 - 4639 (2012);
online-Version: DOI: 10.1002/ejoc.201200322;
The Overcrowded Borazine Derivative of Hexabenzotriphenylene
via Dehydrohalogenation.
Buchkapitel
- B. Speiser in A.J. Bard und I. Rubinstein (Hrsg.),
Electroanalytical Chemistry, Vol. 19,
Simulation of Electroanalytical Experiments by Numerical
Methods -- Recent Advances, Marcel Dekker, New York, 1996, S. 1 - 108.
- B. Speiser, Elektroanalytische Methoden, in
K.E. Geckeler und H. Eckstein (Hrsg.), Bioanalytische und biochemische
Labormethoden, Vieweg, Braunschweig/Wiesbaden, 1998,
S. 301 - 370.
- B. Speiser,
in A.J. Bard und M. Stratmann
(Hrsg.), Encyclopedia of Electrochemistry,
Vol. 3 Instrumentation and Electroanalytical Chemistry
(Bandherausgeber: P. Unwin), Kapitel 2.1: Linear Sweep and
Cyclic Voltammetry, Wiley-VCH, Weinheim, 2003, S. 81 - 104.
- B. Speiser,
in R. Gleiter und H. Hopf (Hrsg.), Modern Cyclophane Chemistry,
Wiley-VCH, Weinheim, 2004, Kapitel 14, Molecular Electrochemistry of
Cyclophanes, S. 359 - 379.
- B. Speiser,
in A.J. Bard und M. Stratmann
(Hrsg.), Encyclopedia of Electrochemistry,
Vol. 8 Organic Electrochemistry (Bandherausgeber:
H.J. Schäfer), Kapitel 1: Methods to Investigate Mechanisms
of Electroorganic Reactions, Wiley-VCH, Weinheim, 2004, S. 1 - 23.
- H.A.Y. Mohammad, J.C. Grimm, K. Eichele, H.-G. Mack, B. Speiser,
F. Novak, W.C. Kaska und H. A. Mayer,
Double Cyclometalation: Implications for C-H Oxidative
Addition With PCP Pincer Compounds of Iridium,
in K.I. Goldberg und A.S. Goldman (Eds.),
,,Activation and Functionalization of C-H Bonds``, ACS Symposium
Series, American Chemical Society,
No. 885, Kapitel 14, S. 234 - 247 (2004).
- B. Speiser, in R.F. Savinell, K.-i. Ota und G. Kreysa (Hrsg.),
Encyclopedia of Applied Electrochemistry, SpringerReference, Springer,
Heidelberg; online-Version:
DOI 10.1007/SpringerReference-303485 2012-06-15 18:14:24 UTC
Numerical Simulations in Electrochemistry.
Buchbesprechungen
- B. Speiser,
Angew. Chem., 105, 1273 - 1274 (1993); Angew. Chem. Intl. Ed.
Engl. 32, 1218 - 1219 (1993);
,,Electron and Proton Transfer in Chemistry and
Biology``, herausgegeben von A. Müller, H. Ratajczak, W. Junge
und E. Diemann.
- B. Speiser,
J. Electroanal. Chem., 374, 280 - 282 (1994);
,,Cyclic Voltammetry. Simulation and Analysis of
Reaction Mechanisms``, von D.K. Gosser Jr.
- B. Speiser,
Angew. Chem., 108, 853 - 854 (1996);
,,Electrochromism. Fundamentals and Applications``, von P.M.S. Monk,
R.J. Mortimer und D.R. Rosseinsky.
- B. Speiser,
Angew. Chem., 109, 2635 - 2636 (1997);
,,Grundlagen der Elektrochemie``, von W. Schmickler.
- B. Speiser, Angew. Chem., 111, 1396 - 1397 (1999);
,,Leitfaden der Elektrochemie``, von R. Holze.
- B. Speiser,
Angew. Chem., 114, 1299 - 1300 (2002),
,,Electrochemical Reactions and Mechanisms in Organic Chemistry``, von
J. Grimshaw.
- B. Speiser,
Angew. Chem., 114, 3652 - 3653 (2002),
,,Electrochemistry in Nonaqueous Solvents``, von K. Izutsu.
- B. Speiser,
Nachr. Chem. Tech. Lab., 51, 53 - 54 (2003),
,,Electrochemical Methods. Guide to Experiments and Applications.``,
herausgegeben von F. Scholz.
- B. Speiser,
Nachr. Chem. Tech. Lab., 51, 54 (2003),
,,Praxis der elektrochemischen Messtechnik. Grundlagen, Schalttechnik,
Experimente.``,
von H.-J. Haase.
- B. Speiser,
Anal. Bioanal. Chem., 389, 1657 - 1658 (2007),
,,Encyclopedia of Electrochemistry, Volume 10: Modified Electrodes``,
von I. Rubinstein, M. Fujihira und J.F. Rusling (Hrsg.).
- B. Speiser,
Nachr. Chem. Tech. Lab., 57, 167 - 168 (2009),
,,Spectroelectrochemistry``,
von W. Kaim und A. Klein (Hrsg.).
Publikationen in Tagungsbänden ohne ISBN1
- B. Speiser, Beiträge zur Klausurtagung der
Materialforschungsprojekte MFI 4 und 5 der Universitäten
Tübingen und Stuttgart, Tübingen, 1990;
Elektroanalytische Simulationen. 12.
Theoretische Analyse von katalytischen Elektrodenreaktionen an
amperometrischen Biosensoren.
- A. Rieker, J. Bracht, P. Hertl und B. Speiser,
Abstracts of the 23
Symposium on Oxidation Processes (Ed.: The Society of Synthetic
Organic Chemistry und The Chemical Society of Japan), 1990, S.
227 - 232; Some Aspects of the Anodic Oxidation of Sterically
Hindered Anilines and Phenols.
- E. Eichhorn, A. Rieker, B. Speiser und H. Stahl,
Proc. 67
Annual Meeting of The Chemical Society of Japan,
1994, S. 184 - 185; Schiff-Base Co-Complexes. Electron-Transfer and
Ligand-Exchange.
in Chem. Abs. referierte ,,Reports``
- B. Speiser und S. Pons, Report TR-8, Order-No. AD-A118708;
Chem. Abs. 98, 62065g (1983);
Simulation of Edge Effects in Electroanalytical Experiments
by Orthogonal Collocation. Part 1. Two-dimensional Collocation
and Theory for Chronoamperometry.
- B. Speiser und S. Pons, Report TR-9, Order-No. AD-A118709;
Chem. Abs. 98, 62063e (1983);
Simulation of Edge Effects in Electroanalytical Experiments by
Orthogonal Collocation. Part II. The Theory for Cyclic Voltammetry
by Collocation.
- B. Speiser, A. Rieker und S. Pons, Report, TR-11,
Order-No. AD-118711; Chem. Abs. 98, 62062d (1983);
Electroanalytical Investigations. - IV.
Use of Orthogonal Collocation for the Simulation of Quasireversible
Electrode Processes under Potential Scan Conditions.
- S. Pons, B. Speiser und J.F. McAleer, Report TR-12,
Order-No. AD-A118712; Chem. Abs. 98, 61975s (1983);
Orthogonal Collocation Simulation of the Rotating Disk Electrode.
- B. Speiser und S. Pons, Report TR-14, Order-No. AD-A118710; Chem. Abs. 98, 62064f (1983);
Simulation of Edge Effects in Electroanalytical Experiments
by Orthogonal Collocation. Part III. Application to
Chronoamperometric Experiments.
- J.F. Cassidy, S. Pons, A.S. Hinman und B. Speiser, Report
TR-23, Order-No. AD-A136988; Chem. Abs. 101, 13949v (1984);
Simulation of Edge Effects in
Electroanalytical Experiments by Orthogonal Collocation. Part 4.
Application to Voltammetric Experiments.
zur Veröffentlichung angenommene oder im Druck
befindliche Publikationen
- A. Ruff, Paul Schuler und B. Speiser,
J. Solid State Electrochem., im Druck;
online-Version: http://dx.doi.org/10.1007/s1008-012-1834-0;
Redox-active Silica Nanoparticles. Part 6. Synthesis and Spectroscopic and
Electrochemical Characterization of Viologen-Modified Stöber Silica
Particles with Diameters of approximately 125 nm.
- V. Gierz, A. Seyboldt, C. Maichle-Mössmer, K.W. Törnroos, M.T. Speidel,
B. Speiser, K. Eichele und D. Kunz,
Organometallics, im Druck;
online-Version: http://dx.doi.org/10.1021/om300544g;
Dinuclear Coinage-Metal Complexes of Bis(NHC) Ligands: Structural
Features and Dynamic Behavior of a Cu−Cu Complex.
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Bernd Speiser
2012-10-14